Iodometry, also known as iodometric titration, is a method of volumetric chemical analysis, involves indirect titration of iodine liberated by reaction with the analyte, whereas iodimetry involves direct titration using iodine as the titrant. What is the Difference Between Iodometry and Iodimetry? In Iodometry two redox reactions occur. In Iodimetry, only one redox reaction process. Iodometry and Iodimetry – Download as Word Doc .doc /.docx), PDF File .pdf), Text File .txt) or read online.

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This is the second redox reaction and it is the reaction used for the titration.


Therefore, iodine reduces to iodide, and iodine will oxidize other species. The standard solution is sodium thiosulfate.

Formula for the determination of sulphur dioxide. Does anybody remember the four types of reactions that we call fundamental analytical reactions?

Feedback Privacy Policy Feedback. For analysis of antimony V compounds, some tartaric acid is added to solubilize the antimony III product. The key difference between iodometry and iodimetry is that we can use Iodometry to quantify oxidizing agents, whereas we can use iodimetry to quantify reducing agents. As mentioned in the definition, this is a direct titration method.

Treatment of experimental data. Until now, most of the titrations that we have performed in the laboratory are direct titrations. Exam 2 on Wed, Nov 3. This titrating species is a standard solution of a reducing agent, which is capable of reducing iodine back to iodide form.


This indicates the end point of the titration. LH is a monosaturated or polyunsaturated acid. Performing the titration cont. This suspension is a watery solution of starch with a few drops of bactericide added to prevent decomposition, as this would stop the starch behaving as an indicator. As the names Iodometry and Iodimetry suggest, they relate to a process where Iodine is involved. Once sulphur dioxide is added to wine it does not remain free but oxidates in part and in part combines with other molecues:.

Thi is another of the advantages of using sulphur dioxide because it guarantees the stability of the product over time.

The iodine, which is stoichiometrically released after reduction of the analyte, is then titrated with a standard sodium thiosulphate solution Na 2 S 2 O 3. The Color Change in Iodometry. Retrieved from ” https: Usually, we use a standard thiosulphate solution for this.

Redox titration using ioximetry thiosulfateNa 2 S 2 O 3 usually as a reducing agent is known as iodometric titration since it is used specifically ioddometry titrate iodine.

Iodometry – Wikipedia

For simplicity, the equations will usually be written in terms of aqueous molecular iodine rather than the triiodide ion, as the iodide ion did not participate in the reaction in terms of mole ratio analysis. Available chlorine refers to chlorine liberated by the action of dilute acids on hypochlorite. Introduction iodimefry iodometric and iodimetric titrations An oxidaizing agent is the element or compound in a redox reaction that oxidaizes another species.

Iodimetry is less common when compared to Iodometry. Iodometric titration of copper Sample: Acid and Base Anhydrides These are compounds that themselves are not acids or base, but when dissolved in water produce an acid or base by reacting with. In an iodometric titration, a starch solution is used as an indicator since it can absorb the I 2 that is released.


First, we should take a known amount of volume from the mixture in which chlorine is dissolved into a titration flask. Introduction to iodometric and iodimetric titrations A reducing agent is the element or compound in a redox reaction that reduces another species. Sulfites and hydrogensulfites reduce iodine readily in iodometfy medium to iodide.

Difference Between Iodometry and Iodimetry

Optical methods of analysis. And a standard solution of this is used for the iodometric titrations. Licensed under Public Domain via Commons.

Introduction to iodometric and iodimetric titrations. Not a direct titration because there are 2 reactions: The term iodimetry, on the other hand, refers to titration using an iodine solution and is useful for determining substances that have reducing properties.

Starch granules stained with iodine — through microscope. The number of equivalents of titrated iodine is the same as the number of anf present in the sample as shown in the reaction in fig.

Awarded from the Generalitat de Catalunya, Slide 1: